”The Role of Humic
Substances in the Ecosystems and in Environmental Protection”
IHSS8 Proceedings edited by J. Drozd, S.S.
Gonet, N. Senesi and J. Weber
copyright © 1997 by PTSH – Polish Society of Humic Substances
the Polish Chapter of
the International Humic Substances Society
Contents
Chemistry and Structure of Humic Substances
Piccolo A. New Insights on the
Conformational Structure of Humic Substances
as Revealed by Size Exclusion Chromatography .................. 19
Davies G., Ghabbour E.A., Khairy A.H., and Ibrahim
H.Z.
A Model for Adsorption
on Humic Acids .................. 37
Tombácz E., Rice J.A., and Ren S. Effect of
Conformational Changes on Aggregation Processes in Humic Acid Solutions
.................. 43
del Rio J.C.,
Czechowski F., Gonzalez-Vila F.J., and Martin F.
Molecular
Composition of Humic Acids from Xylitic and Humic Brown Coals
as Revealed by Pyrolysis Methods Combined with Gas Chromatography-Mass
Spectrometry .... 51
Wang M.C., and Huang P.M. Catalytic Power of Birnessite
in Abiotic Formation
of Humic Polycondensates from Glycine and Pyrogallol.................. 59
Bergh S., Flodin C., Allard B., Borén H., and Grimvall
A.
Pyrolysis GC-MS
and GC-AED Analysis of Aquatic Humus and Hydrophilic Acids .................. 67
Sein L.T. Jr., Kolla S., Varnum J.M., Davies J., and
Jansen S.A.
Conformational
Modelling of a Proposed Building Block of Humic Acid:
Searching Chirally Undefined Conformational Space .................. 73
Ciavatta C., Montecchio D., Francioso O., Manunza B.,
Govi M., and Gessa C. Potentiometric and Spectroscopic Study of Peat Fulvic
Acids .................. 79
Davies G., Fataftah A., Radwan A., Willey R.J., Ghabbour
E.A., and Jansen S.A.
Aerogels: New High Surface Area Forms of Solid Humic Acids .................. 85
Radwan A., Willey R.J., Davies G., Jansen S.A., and
Ghabbour E.A.
Rapid Supercritical Fluid Pre-Extraction of Humic Acids from Plant Sources ..................
91
De Nobili M., Fornasier F., and Bragato G. Capillary
Electrophoresis of Humic Substances in Polyethylenglycole Solutions
.................. 97
Dixon I.R., Hayes M.H.B., Burdon J., and Grocott S.C. Reductive
Degradation
of Humic-Type Substances Isolated from the Bayer Process: A Comparison
between New and Classical Techniques .................. 103
Duteil M.-L., Perie C., Bailly J.-R., and Revel J.-C. On the
Fractionation of Humic
Acids by Gel Permeation Chromatography .................. 109
Filip Z.K., Trubetskoj O.A., and Alberts J.J. Electrophoretic
Comparison of Humic Substances Derived from Natural and Anthropogenic
Environments .................. 115
Flis-Bujak M.,
Ksiê¿opolska A., Stawiñski J., and D¹bek-Szreniawska M.
Microstructure
of Humic- and b-Humic Acids from
Water and N2
Adsorption.................. 121
Kawahigashi M., Fujitake N., Tsurudome T., Suzuki S.,
and Otsuka H.
Configurations and Surface Active Properties of Humic Acid with Increasing
Concentration of NaCl .................. 127
Sanchèz-Cortès S., Francioso O., Ciavatta C., Govi M.,
and Gessa C.
Surface-Enhanced Raman Spectroscopy of Peat Humic Acids Fractions
.................. 133
Hertkorn N., Günzl A., Wang C., Freitag D., and Kettrup
A.
NMR
Investigations of Silylated Humic Substances .................. 139
Hayes T.M., Watt B.E., Hayes M.H.B., Clapp C.E., and
Jakeman P.
Amino Acid and Neutral Sugar Contents of Humic Substances Isolated by Charge
Density Differences .................. 147
Jansen S.A., Kolla S., Sein L.T. Jr., Paciolla M.D.,
Radwan A., Davies G.,
and Varnum J.M. Distribution of Polysaccharides in Humic Acids Derived
from Plant Sources .................. 157
Korshin G.V., Li C.-W., and Benjamin M.M. Studies of Nom
Oxidation by Chlorine
by UV and Fluorescence Spectroscopy .................. 163
Cebulak S., and Pacha J. Oxyreactive Thermal Analysis
in Studies of Organic
Matter Alterations .................. 169
Ricca G., Pastorelli C., and Severini F. Humic Acid from
Leonardite: Structural Investigations and Complexes with Metal
Ions.................. 175
Schmitt P., Hertkorn N., Hoppe A., Garrison A.W., Freitag
D., and Kettrup A.
Capillary
Electrophoresis Methods; New Tools in the Characterization of Humic
Substances .................. 183
Schulthess C.P., Quigley J.S., Dapkus M.J., and Huang
C.P.
Are Our Soil Organic Extractions Too Harsh? .................. 193
Šebestová E., Machoviè V., and Pavlíková H. Structural
Characterization
and Heavy Metal Sorption Properties of Coal Derived Humates Produced
in the Czech Republic .................. 199
Zaujec A., Sima J., and Liptaj T. Transformations of
Organic Matter during
Incubation .................. 207
Miklewska J. A New Insight at Elemental
Analysis of Humic Acids – Factor
Analysis Approach .................. 213
Turnover of Humic Substances in Terrestrial Ecosystems
Amelung W., Flach K.W., and Zech W. Small Scale
Heterogeneity of Organic
Species in Ped Surface and Core .................. 221
Blair G.J., Blair N., Lefroy R.D.B., Conteh A., and
Daniel H. Relationships between KMnO4 Oxidizable C and Soil Aggregate Stability and the
Derivation of a Carbon Management Index........ 227
Ellerbrock R.H., Höhn A., and Rogasik J. Influence of
Management Practice on Soil Organic Matter Composition .................. 233
Hjelm O., and Öberg G. Turnover of Organic Matter
and Formation of Organically
Bound Halogens in Soil.................. 239
Madari B., Michéli E., Johnston C.T., Graveel J.G., and
Czinkota I.
Spectroscopic Investigation of the Effect of No-Till and Conventional Tillage
on Soil Organic Matter .................. 245
Zsolnay Á. The Development of Tests to
Quantify the Potential Ecological
Relevance of the Water Soluble Humus .................. 251
Adamu J., Joe Mbagwu S.C., and Piccolo A. Organic Matter and
Nitrogen
Concentrations in Aggregates of Forest and Cultivated Soils in the Central
Plateau,
Nigeria .................. 257
Zech W., Amelung W., and Neufeldt H. Organic Matter in
Termite Mounds
of the Cerrados, Brazil .................. 263
Klavins M., and Apsite E. Aquatic Humic Substances from
Surface Waters of Latvia .................. 269
Baranèíková G. Influences of Changes in Groundwater
Levels on the Composition
of Humic Acids in a Danube Lowland .................. 283
Beyer L., Blume H.-P., Sorge C., Schulten H.-R., and
Erlenkeuser H.
Humus
Composition and Transformation in a Pergelic Cryohemist of Coastal
Continental Antarctica .................. 289
Buurman P., and Aran D. Relation between Thermal and
Microbial Degradability
in Podzol Organic Matter .................. 295
Candler R., Ping C.L., Michaelson G.J., and Malcolm
R.L.
Characterization of Fractionated Soil Organic Matter from Two Alaskan
Arctic Soils by 13C NMR and Titration Analysis .................. 301
Cheshire M.V., Bedrock C.N., McPhail D.B,. and Fraser
A.R.
The Origin of Free
Radicals in Humic Acid: Increase in the Free Radical Content of Straw
During Humification in Soil .................. 309
Dêbska B. The Effect of Greeen Manure on the Properties
of Soil Humic Acids .................. 315
Fornasier F., and De Nobili M. Effects of
Cultivation and Soil Management
on the Quality of Humic Substances (HS) in Two Tropical Sandy Soils
.................. 323
Ekeh R.C., Mbagwu J.S.C., Agbim N.N., and Piccolo A. Physical
Properties of Two Tropical Soils Amended with Coal-Derived Humic Substances
.................. 329
Gallardo J.F., Martin A., and Santa Regina I. Dynamics of
Organic Fractions
in the Decomposition of Oak and Chestnut Leaves .................. 335
Hanschmann G., Geyer W., Findeisen M., Stärk H.-J., and
Popp P.
Soil
Humic Substances as Indicators of Environmental Impacts .................. 347
Hanes J. The Study of the Changes of Selected Plant
Residues and Their Influence
on Chemical Properties of the Soil .................. 355
Higashi T., and Katayama H. Effects of Larix
Leptolepis Afforestation on Some
Chemical and Optical Properties of Humic Substances in Volcanic Ash Soils
from Central Japan .................. 365
Hüttmann S., and Beyer L. Microbial Utilization of
Humic and Fulvic Acids as Well
as of Water-Soluble Organic Matter of a Podzol in Northern Germany
.................. 373
Jandl R. Biodegradation of Natural Organic Matter -
Interaction with Metals .................. 379
Kaiser K., and Zech W. Structure-Dependent Sorption
of Dissolved Organic Matter
on Soils and Related Minerals .................. 385
Kusiñska A., and Kwasowski W. The Effect of
Invertebrates Macrofauna on the
Process of Grass Litter Mineralization and Humification .................. 391
Lehmann J., Küper U., and Zech W. Organic Matter
Properties of Soils
with Varying Land Use in a Semiarid Tropical Environment .................. 399
Makarov M.I., Malysheva T.I., Zech W., and Haumaier L. Phosphorus
Compounds
in Humic and Fulvic Acids Derived from Various Soils .................. 407
Makarov M.I., Malysheva T.I., Zech W., and Haumaier L. Interaction of
Inorganic Phosphorus with Soil Humic Substances .................. 413
Marchiori M. Jr, and de Melo W.J. Carbon and
Nitrogen in Soil Organic Matter
as Affected by Land Use .................. 419
Masciandaro G., Marinari S., Grego S., and Ceccanti B. Use of Pyrolysis
Technique to Evaluate Changes in Soil Organic Matter Quality Caused
by Mineral and Organic Fertilization .................. 425
Michaelson G.J., Ping C.-L., Candler R., Loya W.M.,
and Malcolm R.L. Comparison
of Fractionated Organic Matter of Leachates and Soils from Arctic Alaska
.................. 431
Miltner A., and Zech W. Changes in Organic Matter
Composition during Incubation
of Beech Litter in the Presence of Minerals .................. 437
Murata T., Tanaka H., Sakagami K., and Hamada R. Seasonal Changes
in Soil
Neutral Sugar Carbon Induced by Organic Material Applications
.................. 443
Norman E.C., Graham C.L., Hayes M.H.B., Grocott S.,
and Skjemstad J.O.
Humic Substances and the Bayer Process .................. 449
Novák F., Machoviè V., Novotná M., Pavlíková H., and
Šebestová E.
Soil Lipids (Bitumens) in Mountain Spruce Forest Soil .................. 457
Pacha J., and Cebulak S. Thermal Analysis of Pine
Needles Decomposing in Soil
Treated with Compounds of Trivalent Chromium .................. 463
Paramonova T.A., and Zech W. Investigation of
Humic Acids Structure from
a Podzol Profile: Wet Chemical and 13C NMR Spectroscopic Data
.................. 469
Ping C.-L., Michaelson G.J., Cherkinsky A., and
Malcolm R.L.
Characterization of Soil Organic Matter by Stable Isotopes and Radiocarbon
Ages of Selected Soils in Arctic Alaska .................. 475
Rumpel C., Kögel-Knabner I., Cebulak S., and Hüttl
R.F.
Organic Matter of Rehabilitated Mine Soils in Lusatia, Germany
.................. 481
Simpson A.J., Graham C.L., Watt B.E., Hayes T.M., and
Hayes M.H.B.
Isolation and Characterization of Humic Substances from the Bh Horizons
of Two Soils with Different Histories of Forest Cover .................. 487
Skiba S., Drewnik M., and Drozd J. Characteristic of
the Organic Matter of
Ectohumus Horizons in the Soils of Different Mountain Regions in Poland
.................. 497
Sk³odowski P., and Szafranek A. The Characteristic
of Organic Matter of Leptic
Podzols and Orthic Luvisols .................. 507
Arlauskas M., and Slepetiene A. Effects of
Conventional and Minimum Soil
Tillage Systems, Diverse Fertilization and Various Crop Rotations on the Humus
Composition of Loamy Soils .................. 513
Zaujec A., and Gonet S.S. The Influence of Farming
Systems on Composition
and Properties of Humic and Fulvic Acids .................. 517
Humic Substances in Aquatic and Sedimentary Systems
Kumke M.U., and Frimmel F.H. NOM - Experienced
by Time-Resolved
Spectroscopy .................. 525
Dahlén J., Allard B., and Borén H. Characterisation
of Humic Substances by
Capillary Zone Electrophoresis .................. 533
Alberts J.J., Filip Z., and Hertkorn N. Interaction of
Light with Estuarine Fulvic
and Humic Acids .................. 539
Cieœlewicz J., and Gonet S.S. Properties of
Sediment Humic Acids of Lakes
of Varied Catchment Management .................. 545
Cieœlewicz J., NiedŸwiecki E., Protasowicki M., and
Gonet S.S. Humus Properties
of Bottom Sediments from the Szczecin Lagoon (North-West Poland)
.................. 553
Claus H., Filip Z.K., and Alberts J.J. Microbial
Utilization and Transformation
of Riverine Humic Substances .................. 561
Davies G., Fataftah A., Radwan A., Willey R.J.,
Ghabbour E.A., and Jansen S. A.
Isolation of Humic Acids from Live Plants .................. 567
Dierckx A., Maes A., Henrion P., and De Cannière P. Potentiometric
Titration
of Humic Substances Extracted from Boom Clay .................. 573
Esteves V.I., and Duarte A.C. The Influence of
Vegetation and Effluent Discharge
from a Pulp and Paper Mill on the Composition of Aquatic Humic Substances
.................. 579
Go³êbiowska D., and Mielnik L. Characteristics of
Humic Acids in Bottom
Sediments of Lobelia Lakes with Different Transparencies .................. 587
Hongve D., and Dahlback A. On the Efficiency of Solar UV
Radiation on
Degradation of Aquatic Humic Substances .................. 595
Parlanti E., Belin C., Texier H., Ewald M., and
Lamotte M.
Interpretation of the Fluorescence Signature of the Marine and Continental
Waters in the Gironde and Seine Estuaries.................. 603
Nagao S., Suzuki Y., Matsunaga T., and Amano H. Characterization
of Humic
Substances in the Kuji River Waters by High-Performance Gel Permeation
Chromatography .................. 611
Nagao S., Matsunaga T., Suzuki Y., Amano H., Kovalev
A.V. and Tkatchenko Y.V.
Fluorescence Characteristics of Molecular Size Fractions of Humic Substances
in River Waters from Chernobyl, Ukraine .................. 617
Suzuki Y., Nagao S., Matunaga T., Amano H., Kovalev
A.V., and Tkatchenko Y.V.
Three-Dimensional Excitation Emission Matrix Spectra of Humic Substances in
Natural Waters .................. 623
Newcombe G., Hepplewhite C., Pelekani C., Drikas M.,
and Snoeyink V.
Comparison of Characteristics of Fractionated NOM from Two Reservoirs
.................. 629
Hayes M.H.B., Kenworthy I.P., Quane M.T., and Watt
B.E.
Influence of Acidification on Humic Substances in the Drainage Waters of the
Watershed of Lake Skjervatjern as Part of the Humex Project .................. 635
Hunchak-Kariouk K., Pedersen J.A., Schweitzer L., and
Suffet (Mel) I.H.
Influence of pH on the Association of 2,2',4,4'-Tetrachlorobiphenyl with
Sediment
Pore Water Dissolved Organic Matter .................. 641
Dunkelberg H., Klöcking H.-P., and Klöcking R. Suppression of
Heat-Induced [3H]Arachidonic Acid Release in U937 Cells by Humic Acid-Like
Polymers .................. 647
Interaction of Humic Substances with Xenobiotics and
Heavy Metals
Hayes T. M., Hayes M.H.B. Considerations of Influences
of Water Soluble Humic Substances on the Solubilities of Anthropogenic Organic
Chemicals .................. 655
Szabó G., Guzi J., and Bulman R.A. Investigations of
the Partitioning of
Anthropogenic Compounds into Humic Substances Immobilized on Silica Gel
.................. 671
Ephraim J.H., and Allard B. Effects of Fulvic
Acid on the Uptake of Metal Ions
by Naturally Occurring Solids .................. 677
Riise G. Interaction of NOM with Trace Metals in a
Dystrophic System Subject
to Artificial Acid Precipitation .................. 683
Spiteller M., and Haider K. Characterization
of the Interaction of Natural Organic
Matter and Xenobiotics .................. 689
Korshin G.V., Ferguson J.F., Lancaster A., and Wu H. Influence of Humic
Substances on the Corrosion of Copper- and Lead-Containing Materials
in Potable Water .................. 697
Lassen P., and Carlsen L. Interactions between Humic
Substances and Polycyclic Aromatic Hydrocarbons .................. 703
Amano H., Watanabe M., Onuma Y., Ueno T., Matsunaga
T., and Kuchma N.D.
Speciation of Cs, Sr and Transuranic Elements in Natural Organic Substances
of Surface Soil Layers .................. 709
Davies G., Fataftah A., Cherkasskiy A., Radwan A.,
Jansen S.A., Paciolla M.,
and Ghabbour E.A. Ash and Metal Free Humic Acids .................. 717
Düker A. Desorption of Lead from Goethite in the Presence
of an Aquatic
Fulvic Acid .................. 723
Payer K., Forgács E., and Cserháti T. Interaction of
Volatile Environmental
Pollutants with Humic Substances as Studied by Gas-Liquid Chromatography
.................. 729
Jakubus M., and Czeka³a J. Decomposition of Seed Hemp
Roots (Cannabis Sativa)
and Its Influence on Copper Share in Lower Silesia Soils - Glogow (Poland)
.................. 735
Varnum J.M., Kolla S., Paciolla M.D., Sein L.T., Jr,
Nwabara S., Kim P.,
Davies G., Smith A., Ghabbour E.A., and Jansen S.A.
Metal Uptake by "Metal-Free" Humic Acid .................. 741
Kalbitz K., Popp P., Geyer W., and Hanschmann G. The Role of
Dissolved
Organic Matter for the Mobilization and Transport of b-HCH from the Topsoil
to Deeper Soil Layers .................. 747
Karczewska A., Spiak Z., Borggaard O.K., and Raben-Lange
B.
Chromate
Sorption and Reduction on Humic Acids and Iron Oxides .................. 753
Klavins M., and Apsite E. Immobilization of Humic
Substances.................. 759
Pavasars I., Ephraim J.H., and Allard B. Complexation of
Europium by an Aquatic
Fulvic Acid: Iron as a Competing Ion .................. 767
Pospíšil F. The Interaction of Humic
Acids with Ascorbate and Chromium .................. 773
Veeken A.H.M., and Hamelers B.V.M. Modelling Proton
and Cu(II) Binding
to Organic Particles Present in Organic Municipal Waste .................. 779
Watt B.E., Burdon J., and Hayes M.H.B. Chlorination
by-Products of Aquatic
Humic Substances .................. 785
Recycling and Utilization of Organic Municipal and
Agricultural Wastes
Chen Y., Chefetz B., Adani F., Genevini P., and Hadar
Y.
Organic Matter Transformation During Composting of Municipal Solid Waste
.................. 795
Filip Z. K. Appearance, Structural
Characteristics and Fate of Humic Substances
in Municipal Wastes .................. 805
Tambone F., Gasperi F., Genevini P., Zorzi G., and
Adani F.
A New Analytical Method for Humic Substances Determination in Organic
Fertilizers and Amendments .................. 811
Veeken A.H.M., and Hamelers B.V.M. Role of Humic
Acids in the Solubility and Reactivity of Cu(II) Present in Organic Municipal
Waste .................. 817
Hänninen K., Kovanen T., and Alén R. Degradation of
Cardboard-Based Liquid
Containers in Composting .................. 823
Beyer L., Fründ R., and Mueller K. Short-Term Effects
of a Secondary Paper Mill
Sludge Application on Soil Organic Matter in a Sandy Soil under Cultivation
.................. 829
Bonmatí M., Gascón X., Pujolà M., and Serra L. Effects of Sewage
Sludge
Addition on Organic Matter Composition and Biochemical Parameters of a Soil
in a Reclamation Field Experiment .................. 835
Dell’Abate M.T., Canali S., Trinchera A., Benedetti
A., and Sequi P.
Evaluation of the Stability of Organic Matter in Composts by Means
of Humification Parameters and Thermal Analysis .................. 841
Drozd J., Jamroz E., Licznar M., Licznar S.E., and
Weber J. Elemental Composition
of Fulvic and Humic Acids during Composting of Municipal Solid
Wastes.................. 847
Drozd J., Jamroz E., Licznar M., Licznar S.E., and
Weber J.
Organic Matter Transformation and Humic Indices of Compost Maturity Stage
During Composting of Municipal Solid Wastes .................. 855
Flis-Bujak M., Baran S., and ¯ukowska G. Characteristics of
Humus Substances
of Variously Composted Organic Materials .................. 863
González-Carcedo S., and Rad C. Recovery of
Enzymatic Organic Fractions
from Municipal Sludge for Soil Application .................. 869
Miikki V.M., and Hänninen K.I. Humification
during Composting of Digested
Sewage Sludge .................. 877
Marques M.O., Melo W.J., Bellingieri P.A., Marreto
G.H., Kanesiro M.A.B.,
Marques T.A., Chelli R.A., and Leite S.A.S. Residual Effect of Sewage
Sludge
on the Fertility of a Soil Cropped with Sugar-Cane .................. 883
Elvira C., Bénitez E., and Nogales R. Physicochemical
Changes and Organic Matter Transformations after Vermicomposting, at Pilot
Scale, of Sludge from a Dairy
Processing Industry .................. 889
Nogales R., Benitez E., Mingorance M.D., Diaz-Marcote
I., and Polo A.
Characterization of Humic Acids and Determination of Trace Elements
by ICP-MS in Dried and Composted Sewage Sludges .................. 895
Crippa L., Ricca G., Zaccheo P., and Goldberg L.F. Chemical and
Spectroscopic Characterization of Carbon and Nitrogen Transformations in
Composting Maize .................. 901
Rudakova I., Ammosova J., Novikov M.N. The Features of
Humification of Sapropel Composts as Non-Traditional Organic Fertilisers
.................. 909
Iakimenko O.S., and Velichenko S.V. Sewage Sludge
Organic Matter
Transformations in Soil in Incubation Experiment .................. 915
Mbagwu J.S.C., and Piccolo A. Effects of Humic
Substances from Oxidized Coal
on Soil Chemical Properties and Maize Yield .................. 921
Effects of Humic Substances on Biological Activity
Tham J., Jansen W., and Rahmann H. Effects of Humic
Material on Aquatic
Invertebrates in Streams of a Raised Bog Complex .................. 929
Ko¿uch J., and Pempkowiak J. Influences of
Marine Humic Substances of
Different Proprties on the Accumulation of Cadmium by the Baltic Mussel
Mytilus Trossulus .................. 937
De Simone C., Piccolo A., De Marco A., and D’Ambrosio
C.
Antimutagenic Activity of Humic Acids of Different Origin .................. 945
Klöcking H.-P. Anticoagulatory Efficacy of
Poly(hydroxy)-Carboxylates .................. 951
Klöcking R., Helbig B., Schötz G., and Wutzler P. A Comparative
Study of the
Antiviral Activity of Low-Molecular Phenolic Compounds and their Polymeric
Humic Acid-Like Oxidation Products.................. 955
Koper J., and Piotrowska A. Phosphatase
Activity and C/Porg Ratio as the Indexes
of Changes of Organic Phosphorus Compounds in a Soil from Moche³ek (Poland) .................. 961
de Melo W.J., André E.M., de Melo G.M.P., Marques
M.O., de Melo V.P.,
Chelli R.A., and Leite S.A.S. Effects of Fertilization with Sewage Sludge on Soil
Urease Activity and Nitrogen Supply to Sorghum .................. 967
Milczarek I. Effects of Humic and Ascorbic
Acids on Ultra-Weak Luminescence
of Field Pea Seedlings and Roots .................. 973
Nardi S., Concheri G., Reniero F., and Dell’Agnola G. Humic Substance
Mobilization by Root Exudates of Two Different Maize Hybrids ..................
981
Muscolo A., and Nardi S. Auxin or Auxin-Like Activity
of Humic Matter .................. 987
Popov A.I., and Chertov O.G. On Humic
Substances as a Direct Nutritive
Components of Plant-Soil Trophic System .................. 993
Author Index
.................. 999